Joint Seminar with Physical/Theoretical Chemistry
Growth of Functional Molecular Materials
Frank Schreiber
University of Tübingen
Date & Time: January 24, 2020, 14:00 pm
Location: Heinrichstraße 28/V, Room 0092
Crystallization and growth, and more generally structure formation, are ubiquitous in nature and technology. A quantitative understanding of these non-uilibrium processes, which can span several orders of magnitude of time and length scales, remains a challenge.
In this talk, we will first provide an overview of general concepts including classical nucleation theory and rate equation approaches to describe growth and illustrate these by simple examples of growth of elemental crystals.
We will then discuss to which extent these basic concepts can be generalized from elemental (atomic, single-component) systems to molecular systems and colloids, with their different interaction potentials and internal degrees of freedom.
This will lead us to the question of new growth phenomena in more complex materials and the need for more elaborate concepts to describe crystallization and growth, as we will demonstrate based on real-time experiments monitoring growth phenomena.
The lecture will try to connect input from theory, simulation, and experiment.
A. C. Dürr et al., Rapid roughening in thin film growth of the organic semiconductor diindenoperylene Phys. Rev. Lett. 90 (2003) 016104
S. Kowarik et al., Real-time observation of structural and orientational transitions during growth of organic thin films Phys. Rev. Lett. 96 (2006) 125504
S. Bommel et al., Unravelling the multilayer growth of the fullerene C60 in real-time Nature Comm. 5 (2014) 5388